Synthesis and characterization of a new materials in form of polymeric blends are presented. For the synthesis the following chemical components were used: bisphenol A glycerolate diacrylate, Pluronic® F-127, methyl methacrylate and Irgacure as UV polymerization initiator. Five samples with different amounts of Pluronic® F-127 and one reference sample without of polymeric dopant were received. The correct course of the reaction polymerization was confirmed by spectroscopic analysis (ATR/FT-IR). The thermal resistance of the samples was examined by thermogravimetric analysis (TG/DTG). Moreover, using by Shore method, hardness of obtained blends was tested. The obtained materials may find potential application as a resistant coating materials.
This study the copolymerization and physico-chemical properties of the new copolymers of meth/acrylic esters: butyl
acrylate (AB), ethylhexyl acrylate (AEH), or methyl methacrylate (MMA) with 2,2,2-trifluoroethyl methacrylate
(TFEMA) used as a dopant are presented. Chemical structures of the copolymers were confirmed by attenuated total
reflection–Fourier transform infrared (ATR/FT-IR) spectroscopy. Thermal properties of the synthesized materials were
investigated by means DSC (Differential Scanning Calorimetry) and TG/DTG analyses. The influence of fluorinated
dopant on the thermal and optical properties of the copolymers were evaluated in detail.
In this paper, synthesis and characterization of new polymeric blends are presented. For copolymerization, the following components: N-vinyl-2-pyrrolidone (NVP), bisphenol A polysulfone (PSU) and bisphenol A glycerolate diacrylate (BPA-A) were used. 2,2-dimethoxy-2-phenyloacetophenone was applied as a photoinitiator. In this method, five polymeric blends with different amounts of PSU were synthesized. Their hardness was investigated using the Shore method. The effect of polysulfone amount on their mechanical and thermal properties was analyzing by means of attenuated total reflectance Fourier-transform infrared spectroscopy (ATR/FT-IR) as well as thermogravimetry and differential thermogravimetry (TG/DTG)
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.