For extreme ultraviolet light lithography to be a viable process for the future development of computer chips, it is
necessary that clean photons are produced at the intermediate focus (IF). To measure the flux at the IF, the Center
for Plasma-Material Interactiosn (CPMI) at the University of Illinois at Urbana-Champaign has developed a Sn IF
flux emission detector (SNIFFED) apparatus that is capable of measuring charged and neutral particle flux at the IF.
Results will be presented that diagnose debris produced at the IF, as well as methods by which this debris can be
mitigated.
Advanced Materials Research Center, AMRC, International SEMATECH Manufacturing Initiative, and ISMI are
servicemarks of SEMATECH, Inc. SEMATECH, and the SEMATECH logo are registered servicemarks of
SEMATECH, Inc. All other servicemarks and trademarks are the property of their respective owners.
System cleanliness is a major issue facing the lithographic community as the prospects of integrating EUV lithography
into integrated circuit manufacturing progress. Mask cleanliness, especially of particles in the sub-micron
range, remains an issue for the implementation of EUV lithography since traditional mask cleaning processes
are limited in their ability to remove nanometer scale contaminants. The result is lower wafer throughput
due to errors in pattern transfer to the wafer from the particulate defects on the mask. Additionally, carbon contamination and growth on the collector optics due to energetic photon interactions degrade the mirror and shortens its functional life. Plasma cleaning of surfaces has been used for a variety of applications in the past,
and now is being extended to cleaning surfaces for EUV, specifically the mask and collector optics, through a process developed in the Center for Plasma-Material Interactions (CPMI) called Plasma Assisted Cleaning by Metastable Atom Neutralization (PACMAN). This process uses energetic neutral atoms (metastables) in addition
to a high-density plasma (Te ≈ 3 eV and ne ≈ 1017 m-3) to remove particles. The PACMAN process is
a completely dry process and is carried out in a vacuum which makes it compatible with other EUV related
processing steps. Experiments carried out on cleaning polystyrene latex (PSL) nanoparticles (30 nm to 500 nm)
on silicon wafers, chrome coated mask blanks, and EUV mask blanks result in 100 % particle removal with a
helium plasma and helium metastables. Removal rates greater than 20 nm/min have been achieved for PSL
material. Similar removal rates have been achieved for the PACMAN cleaning of carbon from silicon wafers
(simulating collector optic material) with 100% removal with helium plasma and helium metastables. The
PACMAN cleaning technique has not caused any damage to the substrate type being cleaned either through
roughening or surface sputtering. Current results of cleaning various particle types from surfaces through the
PACMAN process are presented.
The tin (Sn) debris contamination is one of the technical challenges for the development of high power
EUV light source with Sn fuel with a long lifetime of EUV collectors. The debris mitigation techniques
(DMTs) can considerably minimize the Sn debris coming out of the source thereby reducing the need or
effort for cleaning. However, for HVM, which requires higher EUV power output than today, it is
questionable if the DMTs alone will completely eliminate the Sn contamination. Besides, at abnormal
instances, we also need to clean thick Sn debris from the mirror surface. For this purpose, the Center for
Plasma-Material Interactions (CPMI) at University of Illinois at Urbana-Champaign has developed a
plasma-based Sn cleaning method using chlorine plasma with densities and temperature around ~9×109/cm3 and ~ 4 eV respectively. From the previous studies at CPMI, it was shown that chlorine plasma
etching can remove Sn debris from Ru mirror surface in a fast (> 400 nm/min) and in situ manner. In this
study, we applied the same method to clean Sn contamination on the mock-up collector in our XTS13-35
DPP EUV source system. The mock-up is made of two shells with different gap widths (4 cm, 7.5 cm and
10 cm) in similar size with the actual collector optic. The cleaning rate at different locations on the mockup
was experimentally investigated, and it was found that the cleaning rates vary largely with the distance
from the chlorine plasma in the range of 20 - 100 nm/min. In addition, a simple analytical model to predict
the cleaning rate was developed based on the plasma-surface reactions and the plasma transport. The
model describes how plasma transport, chlorine radical distribution and pumping flow affect the Sn
cleaning rate with chlorine plasma. Finally, the model is then compared to the experimental results and
validated. Based on the knowledge of chlorine plasma and Sn interactions obtained in this study, a remote
plasma cleaning technique was also investigated and the results obtained therein are presented. The
experimental results along with the model predictions will help design an integrated cleaning system for
collector optic in the high power EUV source system for HVM.
At CPMI, we built a prototype portable, modified electrostatic spherical sector analyzer (ESA) device incorporating a neutral detector; investigated its capabilities for measuring energetic neutrals; and report results in this paper. This detector at the IF will contain a quartz crystal microbalance (QCM), Si witness plate for ex situ analysis, a set of microchannel plates (MCPs) with corresponding ion-diverting apparatus, Faraday cup as well as triple Langmuir probe. These detectors will be capable of quantifying total particle flux, neutral particle flux, and charged particle flux. To verify the capabilities of the detector, CPMI constructed a mock collector optic, which was placed inside the experimental chamber attached to CPMI's XTS 13-35 EUV source. This mock-up simulates the reflection of debris created by discharge-produced plasma (DPP), although it will not be capable of reflecting the EUV light. Recent results on the neutral, charged particle flux, and the carbon and oxygen contamination on a Si witness plate out of the line of sight of the Z-pinch are reported in this paper.
For extreme ultraviolet lithography (EUVL) to become a high volume manufacturing technology for integrated
circuit manufacturing, the cleanliness of the system, especially the photomask, is of high importance. For EUV
photomasks, which cannot be protected from contamination by the use of a pellicle, an effective and quick
cleaning technology needs to be ready in order to maintain wafer throughput. There are challenges to extend
current wet cleaning technologies to meet the future needs for damage-free and high efficiency mask cleaning.
Accordingly, a unique process for cleaning particulates from surfaces, specifically photomasks as well as wafers,
has been evaluated at the University of Illinois Urbana-Champaign. The removal technique utilizes a high density
plasma source as well as pulsed substrate biases to provide for removal. Helium is used as the primary gas in the
plasma, which under ionization, provides for a large density of helium metastable atoms present in the plasma.
These metastable helium atoms have on the order of 20 eV of energy which can transfer to particles on the
substrate to be cleaned. When the substrate is under a small flux of ion bombardment, these bonds then remain
broken and it is theorized that this allows the particles to be volatilized for their subsequent removal. 100 %
particle removal efficiency has been obtained for 30 nm, 80 nm, and 200 nm polystyrene latex particles. In
addition, removal rate has been correlated with helium metastable population density determined by optical
emission spectroscopy.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.