In this manuscript, we report on the successful fabrication of high performance polymer light emitting diodes (PLEDs) using a low temperature, plastic lamination process. Blue- and red-emitting PLEDs were fabricated by laminating different luminescent polymers and organic compounds together to form the active media. This unique approach eliminates the issue of organic solvent compatibility with the organic layers for fabricating multi-layer PLEDs. In addition, a template activated surface process (TAS) has been successfully applied to generate an optimum interface for the low temperature lamination process. The atomic force microscopy analysis reveals a distinct difference in the surfaces created by the TAS and the spin-coating process. This observation coupled with the device data confirms the importance of the activated interface in the lamination process.
We present a successful demonstration of controllable patterning of dual-color polymer light-emitting pixels using a hybrid inkjet printing technique. In this demonstration, the polymer buffer layer is a wide bandgap, blue emitting semiconducting polymer (PPP-NRt3+), prepared by the spin-casting technique. The inkjet printed layer is a red-orange semiconductor polymer, (MPS-PPV) which was printed onto the buffer layer.When a proper solvent was selected, MPS-PPV diffused into the buffer layer and efficient energy transfer took place from the PPP-NEt3+ to the MPS-PPV generating a red-orange photoluminescence and electroluminescence from the inkjet printed sites. Based on this principle, blue and orange-red dual-color polymer light-emitting pixels were fabricated on the same substrate. The use of this concept represents an entirely new technology for fabricating polymer multicolor displays with high-resolution, lateral patterning capability.
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