Optical fibers made of fused silica have many applications like telecom, industrial, medical, or spectroscopy. These applications are as varied as are the requirements for the fibers. Large core step index multimode fibers made of high purity fused silica core and fluorine doped silica cladding are common standard in industrial high-power laser, minimal invasive medical and spectroscopic applications. One of the biggest factors influencing fiber performance is the utilized fused silica core material and its composition. Hydroxyl groups and trace impurities, for example, can influence the transmission properties of the fiber. But also, defect centers created by strong UV radiation or drawing induced absorption bands define the performance over time. Therefore, the choice of the right material is key for high performing fibers. In addition, the height of the refractive index step between the core and the cladding, which defines the numerical aperture, as well as the cladding thickness and cross section design of the fiber are important factors which should be balanced against performance and costs. Depending on the application wavelengths and performance requirements, different fused silica materials and fiber designs are recommended tailored to the application. We will present deeper insights in the optical properties of different fused silica materials and new silica material developments dedicated for the increasing utilization of blue and green lasers to give a guideline to choose the best fiber type depending on the application wavelengths.
Plasma outside deposition (POD) allows the incorporation of high fluorine contents in silica glass to manufacture multi-mode fibers. Due to all silica design and excellent material attributes, these so-called Fluosil fibers cover a wide spectrum of applications over a broad wavelength rage from UV to NIR including medical laser surgery, industrial materials processing, automotive, sensing, spectroscopy, and fiber bundles. These characteristics have allowed fiber designs to become more and more sophisticated in recent years. An overview of the current capabilities, characterization techniques, and fiber trends will be presented. Heraeus supports these new developments by offering a growing number of materials, preforms and services.
In this paper, we present our current work towards a highly efficient XLMA (extra-large mode area) fiber-based laser, which is being performed in the EKOLAS consortium within the BMBF-funded EffiLAS (efficient high-performance laser beam sources) research alliance. To this end, the complete manufacturing process chain of the XLMA fiber was reviewed and optimized. The work started with the material composition of the active XLMA preform with the goal of improving the purity and thus the background loss. A successfully implemented fluorine co-doping process allows refractive index adjustment of the active core material which improves the beam quality of the laser fibers without changing the concentration of active ions in the glass composition. The preform is subjected to a screening in which possible scatter centers, e.g. bubbles, inclusions or contaminants, are mapped and categorized, in order to identify defects, which could lead to a failure in the drawn fiber, already at an early production stage. The subsequent fiber drawing is monitored for scattering using the emissions from the heated preform as well as for inhomogeneities of the dopants using a phase measurement technique. Finally, the fiber is tested for residual impurities and background losses using a multi-mode OTDR to ensure that the fibers are free of any defects.
Space bound as well as earthbound spectroscopy of extra-terrestrial objects finds its challenge in light sources with low intensities. High transmission for every optical element along the light path requires optical materials with outstanding performance to enable the measurement of even a one-photon event. Using the Lunar Laser Ranging Project and the LIGO and VIRGO Gravitational Wave Detectors as examples, the influence of the optical properties of fused silica will be described. The Visible and Infrared Surveillance Telescope for Astronomy (VISTA) points out the material behavior in the NIR regime, where the chemical composition of optical materials changes the performance. Special fibers are often used in combination with optical elements as light guides to the spectroscopic application. In an extended spectral range between 350 and 2,200 nm Heraeus developed STU fiber preforms dedicated for broad band spectroscopy in astronomy. STU fibers in the broad spectral range as well as SSU fibers for UV transmission (180 – 400 nm) show also high gamma radiation resistance which allows space applications.
Laser fusion projects are heading for IR optics with high broadband transmission, high shock and temperature resistance, long laser durability, and best purity. For this application, fused silica is an excellent choice. The energy density threshold on IR laser optics is mainly influenced by the purity and homogeneity of the fused silica. The absorption behavior regarding the hydroxyl content was studied for various synthetic fused silica grades. The main absorption influenced by OH vibrational excitation leads to different IR attenuations for OH-rich and low-OH fused silica.
Industrial laser systems aim for the maximum energy extraction possible. Heraeus Quarzglas developed an Yb-doped fused silica fiber to support this growing market. But the performance of laser welding and cutting systems is fundamentally limited by beam quality and stability of focus. Since absorption in the optical components of optical systems has a detrimental effect on the laser focus shift, the beam energy loss and the resulting heating has to be minimized both in the bulk materials and at the coated surfaces. In collaboration with a laser research institute, an optical finisher and end users, photo thermal absorption measurements on coated samples of different fused silica grades were performed to investigate the influence of basic material properties on the absorption level.
High purity, synthetic fused silica is as well the material of choice for optical components designed for DUV applications (wavelength range 160 nm - 260 nm). For higher light intensities, e.g. provided by Excimer lasers, UV photons may generate defect centers that effect the optical properties during usage, resulting in an aging of the optical components (UV radiation damage). Powerful Excimer lasers require optical materials that can withstand photon energy close to the band gap and the high intensity of the short pulse length. The UV transmission loss is restricted to the DUV wavelength range below 300 nm and consists of three different absorption bands centered at 165 nm (peroxy radicals), 215 nm (E’-center), and 265 nm (non-bridging oxygen hole center (NBOH)), which change the transmission behavior of material.
We report on the fluorine incorporation in powder based materials for the fabrication of Al and Al/Yb co-doped silica glasses. The achieved maximum Fluorine concentration of 1.55 mol% SiF4 corresponds to a refractive index decrease of -8 x 10-3. Simultaneously, the Tg of the doped material is reduced by about 200 K compared to pure silica. Moreover, the fluorine doping is also eminently suitable for the direct refractive index adjustment in active doped silica glass materials (e.g. Al/Yb or Al/Tm). The index matching with pure silica is possible to date up to 2.7 mol% Al2O3 and 0.1 mol% Yb2O3. The additional influence on the blue shift of the UV transmission will also be discussed.
The plasma outside deposition (POD) process is the basic technology for production of large core multimode silica fibers with highly fluorine doped cladding. Due to the all silica fiber construction such fibers can transmit several 10 kW of light power even with a core of 100 μm or less. An overview of the current capabilities and trends in high power laser applications will be presented, including very large fibers, shaped core and cladding designs and fibers with multiple claddings or multiple cores. These concepts can be applied to transmission fibers as well as fiber lasers. Heraeus is supporting these new developments by offering a growing number of materials, preforms and services.
XLMA fibers based on Yb-doped bulk silica possess an excellent refractive index and doping level homogeneity [1]. To
achieve the highest optical-to-optical efficiency and long-term operation without degradation we simulated the effect of the brightness conversion factor of different core dopant compositions of such XLMA fibers. We also investigated the beam quality of a multi-kW single XLMA fiber laser system and its long-term stability. The current state-of-the-art
XLMA single fiber laser has 5 kW maximum output power and a degradation rate of about 0.5 % / 500 h at 4 kW
measured over a period of 1700 h. Several application tests demonstrate the excellent performance of the XLMA fiber
laser.
The quality of Yb-doped fused bulk silica produced by sintering of Yb-doped fused silica granulates has improved
greatly in the past five years [1 - 4]. In particular, the refractive index and doping level homogeneity of such materials
are excellent and we achieved excellent background fiber attenuation of the active core material down to about 20 dB/km
at 1200 nm. The improvement of the Yb-doped fused bulk silica has enabled the development of multi-kW fiber laser
systems based on a single extra large multimode laser fiber (XLMA fiber).
When a single active fiber is used in combination with the XLMA multimode fiber of 1200 μm diameter simple and
robust high power fiber laser setups without complex fiber coupling and fiber combiner systems become possible. In this
papper, we will discuss in detail the development of the core material based on Yb-doped bulk silica and the
characterization of Yb-doped fibers with different core compositions.
We will also report on the excellent performance of a 4 kW fiber laser based on a single XLMA-fiber and show the first
experimental welding results of steel sheets achieved with such a laser.
Sintering of Yb-doped fused silica granulates is a well established technique developed by the IPHT and Heraeus
Quarzglas and it produces very homogeneous rare earth doped bulk silica core rods for fiber laser applications. By using
a newly developed laser induced deflection (LID) technique we are able to pre-characterize directly the material
absorption properties of the bulk material prior to the laser fiber production. The bulk absorption results measured by
LID are without scattering effects and they are typically in good agreement with the total attenuation measured in the
fibers. We achieved a fiber background loss of 20 dB/km. Furthermore, we present detailed studies of the refractive
index homogeneity of the Yb-doped bulk materials and laser fibers to show the unique features of the Yb-doped bulk
silica.
Multimode double cladding laser fibers with an extra large mode area XLMA fiber design (core diameter up to 100 μm)
have been produced from the Yb-doped bulk silica rods by two different techniques. One is a classical jacketing method;
the other employs the stacking of un-doped, Yb- and F-doped rods and F-doped tubes.
Different fiber types have been tested in different fiber laser setups. The influence of the fiber end cap properties on the
fiber laser focus shift is discussed in detail. We have achieved fiber laser output powers up to 1.925 kW, limited only by
the pump power. We also investigated the long term laser stability at different power levels.
Two different concepts are introduced and compared to measure for the first time residual absorption in pure and doped
fused silica fiber preform raw materials at 940 nm and 1550nm directly by means of the laser induced deflection (LID)
technique in order to analyze the minimal achievable attenuation in high power fiber lasers based on the doped fused
silica raw materials.
It is found, that attaching a thin disk sample of the preform raw material to a practically non-absorbing substrate at the
wavelength of investigation is the best measurement concept with respect to material consumption, absolute calibration
and impact of the strong scattering in the doped raw materials on the measurement.
For several Yb doped laser active raw materials the initial absorption value at 1550 nm (ranging from less than 50 dB/km
to about 1800 dB/km) is compared to the total loss achieved for the manufactured fiber at 1200 nm, 1315 nm and 1600
nm, respectively. For some of the chosen materials the fiber loss is very comparable to residual raw material absorption
indicating that the initial absorption is the dominant loss mechanism in the manufactured fiber. In contrast, for some
fibers the total loss exceeds the values of the raw material absorption which allows the conclusion that additional loss
mechanism like scattering, stress, geometrically fluctuation and micro or macro bending contributes to the fiber
attenuation.
At the Photonics West 2008 we presented our rare earth doped fused bulk silica for fiber laser applications [1]. This
approach overcame the typical geometrical limitations of other well known production methods for rare earth doped
silica materials. Our unique production technique is based on the sintering of Yb-doped granulates of high-purity SiO2
particles. We have processed our Yb-doped bulk silica rods into ultra large mode area (XLMA) multi-mode double
cladding laser fibers with an active core diameter in the range of 40 μm to 100 μm (depending on the core doping level).
In the XLMA fiber the active core is surrounded by a so-called 2D- or 4D-shaped pure silica pump cladding (with
diameter between 850 μm and 900 μm) and an F-doped outer silica cladding with an outer diameter of 1000 μm.
We have investigated the refractive index and the intrinsic stress profiles of different XLMA laser fibers and their
preforms to visualize interface effects. The fiber cross section designs, the quality of all interfaces and the material
composition are important factors for the laser fiber performance. The laser properties of these fibers have been
investigated in detail. In addition, the preparation of the fiber end-face is important to reduce heat effects and we have
developed concepts to mitigate such thermal load at the fiber end face.
We have developed a production process for rare earth doped bulk silica to fulfill the demand of such material for fiber
laser applications. In contrast to the standard techniques such as a combination of MCVD (modified chemical vapor
deposition) and solution doping, our novel technology is based on a granulate process that enables novel ultra large mode
area fiber designs (XLMA) with active core diameters above 100 μm as well as larger batch sizes. Several Yb-doped
fibers with two different fiber designs were manufactured and successfully tested in both side- and end-pumped fiber
laser setups. Both fiber designs have been compared to similar MCVD fibers. The influence of the material composition
on the photodarkening properties has been investigated.
We have developed a new technique to produce a Yb-doped fused silica bulk glass which is very well suited for fiber
laser applications. The starting point is a liquid suspension of SiO2 particles which is doped by a solution of rare earth
ions. After dehydration, purification and vitrification we achieve a bubble-free homogeneous Yb-doped fused bulk silica,
which is further processed by the plasma outside deposition (POD) technique into preforms for active laser fibers with a
large active fiber core. The laser function of our Yb-doped silica was successfully proved in a side-pumped fiber laser
setup. We present the results of the laser experiments.
Deep UV application of optical fibers has been restricted due to the strong photodegradation in silica fibers transmitting deep UV light. We have developed an improved all silica preform for the production of multimode fibers with drastically improved resistance to UV-light. Two key experiments have been performed in order to characterize the solarization behavior of such fibers: (1) ArF-excimer laser and deuterium lamp photodegradation spectroscopy enables the in situ observation of defect center creation. (2) Long time photodegradation excimer laser experiments (ArF and KrF) are a good tool to predict the fiber's lifetime for applications with such lasers. Compared to standard high OH all silica fibers the optimized fibers show an exceptionally low creation of E'-centers (215 nm). Hydrogen doping of such fibers further increases the UV-resistance: Even after prolonged excimer laser irradiation (ArF: 20 X 106 pulses, 5 mJ/cm2, 400 Hz; KrF: 20 X 106 pulses, 50 mJ/cm2, 500 Hz) these fibers maintained their very high initial transmission, neither E'-center nor NBOH-center (265 nm) absorption could be observed.
Optical fibers with broadband transmission from the UV through the IR have not been available because the silica core material either has OH absorption bands in the IR or UV absorption due to intrinsic structural defects or chlorine. We have developed a new silica core material which can be fabricated into an optical fiber with very good transmission characteristics from 350 nm to 2000 nm. The transmission performance is stable with time because the fiber is not doped with hydrogen.
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