This talk highlights advances in the growth of new single crystal fiber materials with potential laser applications. Of particular interest are lutetia based single crystal fibers and Yb doped analogs. The Yb:Lu2O3 materials are attractive because the high thermal conductivity of Lu2O3 single crystals is not significantly reduced by doping with Yb in any concentration. The growth of faceted, single crystal 5-10% Yb:Lu2O3 fibers by LHPG is discussed. Also included are early attempts in hydrothermal single crystal cladding of undoped Lu2O3 onto the faceted core.
All-solid-state deep UV lasers (266nm and shorter) have many potential applications including metrology, LIBS, imaging, chem/bio standoff detection, ARPES spectroscopy, and laser surgery. There are few suitable direct laser emission lines at such short wavelengths, making the use of frequency generation by harmonic generation an important tool for UV solid state laser development. The primary limitation of the field is the development of suitable single crystals for nonlinear frequency conversion. The materials must be acentric, have bandgaps substantially wider than the desired conversion line and and be capable of phase matching to these short wavelengths. Several borate crystals have been reported as possible candidates for deep UV nonlinear applications. These include compounds with the formula ABBF (ABe2BO3F2) where A = K, Rb or Cs, and SBBO (Sr2Be2B2O7). Both compounds have very attractive properties for deep UV nonlinear applications including acentric crystal structures, wide band edges, moderate birefringence and reasonable nonlinear coefficients. Both classes are difficult to crystallize and process however. They have two dimensional structures making them somewhat soft, difficult to cut and polish at a critical angle, and making them prone to disorder. The ABBF phases have very attractive optical properties with wide bandgaps and are capable of frequency conversion to 175nm. They are extremely difficult to grow as single crystals however and are extremely soft and difficult to process. To date these are debilitating limitations. The SBBO crystals appear to have nearly as attractive properties with somewhat less of a bandgap than KBBF, but appear to have greater NLO coefficients. They are considerably harder than KBBF but are prone to severe disorder.
Recently the application of hydrothermal methods led to the crystal growth of both of these classes of compounds. The hydrothermal growth of KBBF and RBBF led to formation of large single crystals that can be used for new cutting and polishing methods enabling their use in applications such as ARPES. The hydrothermal growth of SBBO greatly reduces the disorder in the crystals enabling a more confident determination of their optical properties. The recent structural redetermination of SBBO and the examination of their optical properties will be discussed.
The hydrothermal crystal growth technique is developed for the growth of epitaxial single crystal layers on YAG. High
quality epitaxial layers of functionalized layers can be grown using Y2O3 doped with the desired ion and Al2O3 as
feedstocks in water between 600-650°C at 1 kbar pressure, with a mineralizer of 1-4M K2CO3.The epitaxial layers are
doped with a variety of doping ions that enable a number of optical functionalities. These include undoped regions to
serve as endcaps, Q-switching regions, ASE suppression cladding layers, waveguide layers and a number of other
applications. Different layers can be grown sequentially on the same crystal to create multifunctional single crystals.
Epitaxial layers have been grown on both {111} and {100} faces with rates of growth being {100}>{111}>{110}.
Growth rates range typically from 25 to 100 microns per day but faster and slower rates have been observed. The
technique is not restricted to YAG and can be extended to any oxide hosts that can be grown hydrothermally. Work is
being extended to LuAG, YVO4 and M2O3 (M = Lu, Sc).The techniques presented here can address
long-standing
performance issues associated with solid-state laser materials; when combined with crystal joining technologies, new
crystal functionalities emerge that can further improve solid-state laser performance; we refer to this new generation of
laser crystals as "smart".
Cryogenic Yb:YAG lasers operating at 1029 nm have been demonstrated at Snake Creek Lasers with high average
power CW and ultrafast output powers, and provide near diffraction-limited output beams that are ideal for applications
in harmonic generation. We describe experiments that have produced high average power green output power at 515 nm
as well as preliminary experiments producing UV output power at 257.25 nm. Frequency doubling experiments used a
20 mm long non-critically phase-matched LBO crystal mounted in a constant temperature oven. A mode-locked Yb fiber
laser operating at 50 MHz was used to drive a two Yb:YAG cryogenic amplifier system, producing hundreds of watts of
average power output with a FWHM pulsewidth of 12 ps. Doubling efficiencies of > 50 % have been observed. For
frequency quadrupling, we have used hydrothermally grown KTTP crystals grown at Clemson University and Advanced
Photonic Crystals. KBBF offers unprecedented UV transmission down to 155 nm, and was used in a Type I phasematching
configuration. The properties of KBBF will be discussed, as well as the experimental results observed and
conversion efficiency.
Recently developed glass-clad crystalline semiconductor core optical fibers potentially offer a series of
advantages over present optical fiber materials including greatly enhanced Raman cross-sections and extended
infrared transparency. Indeed, the low-cost high-through-put fiberization of crystalline materials could permit a
step-jump in performance critical for use in high energy laser, infrared counter-measure, communication, and
sensor systems. Further, the high degree of crystallinity is of considerable scientific value since optical fiber
fabrication is a highly non-equilibrium process and so achieving high degrees of crystallinity is very counter-intuitive
and offers new insight into crystal growth mechanisms. This talk will review progress in glass-clad fibers
possessing cores of highly crystalline silicon and germanium including anomalies in Si and Ge that may benefit
fiber fabrication as well as paths forward to optimization of fiber design and performance.
The properties of glass-clad fibers containing cores of phase pure and highly crystalline
silicon and germanium are reviewed. Although further optimization is required, losses of about 4
dB/m have been achieved at 3 μm and suggest that such semiconductor core fibers could be of
practical value for nonlinear and infrared applications.
This paper discusses the hydrothermal synthesis of doped and undoped Sc2O3 single crystals as well as Y2O3 and Sc2O3
nanoparticles as high purity precursors to polycrystalline laser hosts.
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