KEYWORDS: Etching, Extreme ultraviolet lithography, Photoresist materials, Lithography, Extreme ultraviolet, Oxygen, Polymers, System on a chip, Line edge roughness, Scanning electron microscopy
Extreme ultraviolet (EUV) exposure is among the front-runners for single-exposure lithography for the 16-nm
node and below. Previous work has shown that assist layers are critical for performing EUV lithography. Assist layers
enhance the adhesion of EUV photoresists, block substrate contamination, and improve the resolution, line width
roughness, and sensitivity (RLS) trade-off. As we progress from development to manufacturing, materials must mature
to align with industry needs. To bring devices produced using EUV lithography to reality, a trilayer process is the best
and most flexible option. The requirements for a trilayer process include utilizing assist layers with a good etch
selectivity to the carbon-rich etch transfer layer (ETL) and to the photoresist coupled with good RLS performance. In
this paper, we report the study of new assist layers made with novel resins that have shown superior lithography
performance, as well as high etch selectivity to both the ETL and the photoresist. We have demonstrated how to
significantly improve the lithography with the benefits of the pattern transfer requirements for trilayer processing.
Traditional implant layers are becoming increasingly complex in design and continuously pushing
resolution limits lower. In response, developer-soluble bottom anti-reflective coatings (DBARCs) were
introduced to meet these more challenging requirements. These DBARCs excelled over the traditional
combination of single-layer resist and dyed resist/top anti-reflective coating (TARC). DBARCs offered the
resolution and critical dimension (CD) control needed for the increasingly critical implant layers.
Lithographic performance, focusing on CD control over topography and through-pitch behavior,
demonstrated the inherent benefit of the DBARCs over the alternative solutions. Small-space residue
testing showed the benefit of photosensitive (PS) DBARCs for cleanout of sub-100 nm trenches. A study
of improved post-develop residue in various ion-implantation processes validated the use of new DBARC
materials in implant layers.
Developer-soluble bottom anti-reflective coating (DBARC) BSI.W09008 has provided promising lithography results
with five different 193-nm photoresists, with the accomplishments including 120-nm L/S (1:1) and 130-nm L/S
through-pitch (i.e., 1:1, 1:3, and isolated line). This DBARC is not inherently light sensitive and depends on diffusing
photoacid from the exposed photoresist for development. With undercutting being an issue for the PAG-less DBARC
with some resists, the shapes of 130-nm lines (both dense and isolated) were improved by either a) incorporating a small
amount of a base additive in the BSI.W09008 formulation or b) altering the structure of the DBARC's binder polymer.
With selected photoresist(s) and/or resist processing conditions, either photoacid diffusion or photoacid activity is
inadequate to give DBARC clearance and BSI.W09008 performs more as a dry BARC. The post-development residue
obtained from BSI.W09008 on a silicon substrate is much less dependent on the initial DBARC film thickness and the
exposure dose than for earlier-generation photosensitive (PS)-DBARC BSI.W07327A, using the same photoresist.
BSI.W09008 also gives less post-development residue than BSI.W07327A using the same resist on a silicon nitride
substrate at exposure doses of 14-25 mJ/cm2.
Minimizing defects in spin-on lithography coatings requires a careful understanding of the interactions between the spin-on
coating material and the filtration and dispense system used on the coating track. A wet-developable bottom anti-reflective
coating (BARC) was examined for its interaction with polyamide and UPE media when utilizing the Entegris IntelliGen Mini dispense system. In addition, a new method of priming the filter and pump is described which improves
the wetting of the filter media, preventing bubbles and other defect-generating air pockets within the system. The goal is
to establish plumb-on procedures that are material and hardware specific to avoid any defect problems in the coating
process, as well as to gain a better understanding of the chemical and physical interactions that lead to coating defects.
Liquid particle counts from a laboratory-based filtration stand are compared with on-wafer defects from a commercial
coating track to establish a correlation and allow better prediction of product performance. This comparison in turn will
provide valuable insight to the engineering process of product filtration and bottling at the source.
A novel approach to developer-soluble bottom anti-reflective coatings (BARCs) for 248-nm lithography
was demonstrated. The BARC formulations are photosensitive, dye-filled systems incorporated with a
polymer binder. The films are generated by thermally crosslinking the polymer matrix, and are then
photochemically decrosslinked in order to render them soluble in developer solutions. The BARCs are
compatible with solvents commonly used in the industry. Easy modification of the films with regard to
optical properties for potential use with various substrates was also demonstrated. The BARCs exhibit
anisotropic development in aqueous tetramethylammonium hydroxide (TMAH) solutions subsequent to
simulated photoresist application, exposure, and post-exposure bake.
This paper describes a new approach to help overcome the challenges of fabricating leading-edge devices by
using the trench first dual damascene process. Wet gap-fill materials are designed to reduce film thickness bias across a
wafer while keeping wafers in the same track in which they were coated. As the first process step, the wafer is coated
with a thick layer of wet gap-fill material to fill all trenches, thus guarding against resist pooling in the trenches. The
substrate is then baked to partially cure the wet gap-fill material. Standard 0.26N tetramethylammonium hydroxide
(TMAH) is then used to wet etch the wet gap-fill layer back to the substrate surface. For this study, substrates with
different trench depths and widths were processed, cross-sectioned, and measured. The effect of trench dimensions and
aspect ratio on the develop properties of WGF200-343 was investigated to see if it could be used as a wet trench-fill
material. This work will help develop a process that will allow the use of trench-first DD processing in modern
semiconductor manufacturing.
This paper describes the chemistry and performance of a new family of wet-developable (wet) bottom anti-reflective coatings (BARCs) that have been developed for 193-nm implant layer applications. These BARCs, which are light sensitive and positive working, are imaged and developed in the same steps as the covering 193-nm photoresist. The BARCs are spin coated from organic solvents and then insolubilized during a hot plate bake step. The resulting cured films exhibit minimal solubility in numerous organic solvents. Resolution of a photoresist A and light-sensitive BARC I at optimum exposure (Eop) on a silicon substrate was 150-nm L/S (1:1), with good sidewall angle and no scumming. These best-case results utilize a first reflectivity minimum BARC thickness and meet the desired resolution goals for noncritical implant layers. BARC optical parameters can easily be adjusted by altering the polymeric binder. PROLITHTM modeling shows that near zero reflectance can be achieved on a silicon substrate for both a first and a second reflectivity minimum BARC thickness. The light-sensitive, wet BARCs are both spin-bowl and solution compatible with most industry standard solvents. A selected BARC from this family of wet products was shown to be stable, providing reproducible film properties over several months of ambient storage conditions.
This paper discusses a novel approach of using a developer-soluble gap fill material, wherein the gap fill material is coated in a layer thick enough to planarize all the topography and is then recessed using a standard 0.26N TMAH developer. The material recess process takes place in the same coater track where it is coated and therefore simplifies the process and increases wafer throughput. Performance and properties of two types of developer-soluble gap fill materials (EXP03049 and NCA2528) based on two different polymer platforms will be discussed in detail.
The via-first process is unique by the fact that a material is needed to fill the vias to some arbitrary value, with little or no isolated-dense via bias so that the underlying layer underneath the via is protected from the trench etch step. Secondly, this material may have to coat over the surface of the wafer with some chosen thickness again with minimum or no bias to maximize the trench photolithography process window. Finally, the material must be easily removed from the via after the trench etch with no residue, crowning, or fencing. The ideal via fill material would be able to perform all the above listed parameters, but no perfect solution exists yet. The etchback process that is discussed herein, called the solvent etchback (SOLVE) process bypasses these lengthy modules, will fit within today’s manufacturing processes and will have little impact on throughput of the photobay coating tools. The process utilizes industry standard photoresists solvents such as PGMEA, Ethyl Lactate, PGME and existing solvent prewet dispense nozzles in the BARC coater module. Also, this process only requires one material that can both fill the via and act as a BARC during the trench photo step with a user defined thickness on top the wafer that will minimize light reflections coming from the substrate. The process flow for the SOLVE process is: 1. Coat a wafer with a thick BARC to planarize the wafer and minimize isolated-dense bias. 2. Bake the BARC so that it is partially crosslinked.
3. Apply a solvent to the wafer and etchback the BARC to a thickness that suits the trench photo step. 4. Bake the BARC to fully crosslink the BARC. Process variables that can have an affect on the SOLVE process are the softbake temperature and time to modify the BARC thickness on the wafer. Dispense parameters that will modify the post-etch uniformity of the wafer include the dispense time, dispense spin speed and the IDI M450 dispense pressure. The repeatability of the process can be modified by changing the solvent spin off speed and acceleration.
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