Synthesis and properties of 1,3-dioxo-1[i]H[/i]-inden-2(3H)-ylidene fragment and (3-(dicyanomethylene)-5,5-dimethylcyclohex-1-enyl)vinyl fragment containing derivatives of azobenzene for holographic recording materials

Elmars Zarins; Valdis Kokars; Andris Ozols; Peteris Augustovs

doi:10.1117/12.886598

11 May 2011 Synthesis and properties of 1,3-dioxo-1H-inden-2(3H)-ylidene fragment and (3-(dicyanomethylene)-5,5-dimethylcyclohex-1-enyl)vinyl fragment containing derivatives of azobenzene for holographic recording materials

Elmars Zarins, Valdis Kokars, Andris Ozols, Peteris Augustovs

Author Affiliations +

Proceedings Volume 8074, Holography: Advances and Modern Trends II; 80740E (2011) https://doi.org/10.1117/12.886598
Event: SPIE Optics + Optoelectronics, 2011, Prague, Czech Republic

Abstract

New glassy 1,3-dioxo-1H-inden-2(3H)-ylidene fragment und (3-(dicyanomethylene)-5,5-dimethylcyclohex-1-enyl)vinyl fragment containing push-pull type derivatives of azobenzene able to create thin layers have been synthesized. Thin films of synthesized glasses for holographic recording were prepared using spin coating technique from saturated chloroform solution. Holographic grating recording in films of 6a-b, 7 and 12 has been experimentally studied at 633 and 532 nm in both transmission and reflection modes with p-p recording beam polarizations. The film 12 was found to be the most efficient at both wavelengths in transmission mode exhibiting the maximum self-diffraction efficiency of 9.9% at 633 nm, and 15.3% at 532 nm. The film of 6a was the most efficient in reflection mode with the maximum selfdiffraction efficiency of about 3%.

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Elmars Zarins, Valdis Kokars, Andris Ozols, and Peteris Augustovs "Synthesis and properties of 1,3-dioxo-1H-inden-2(3H)-ylidene fragment and (3-(dicyanomethylene)-5,5-dimethylcyclohex-1-enyl)vinyl fragment containing derivatives of azobenzene for holographic recording materials", Proc. SPIE 8074, Holography: Advances and Modern Trends II, 80740E (11 May 2011); https://doi.org/10.1117/12.886598

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