Projectors theory use for research into molecular parameters of excited vibrational states

Svetlana P. Gavva

doi:10.1117/12.545617

12 January 2004 Projectors theory use for research into molecular parameters of excited vibrational states

Svetlana P. Gavva

Proceedings Volume 5311, 14th Symposium on High-Resolution Molecular Spectroscopy; (2004) https://doi.org/10.1117/12.545617
Event: 14th Symposium on High-Resolution Molecular Spectroscopy, 2003, Krasnoyarsk, Russian Federation

Abstract

Within the framework of the algebraic disturbance method for eigenvalues and eigenvectors using the projectors theory, a research into the structure parameters of molecules excited vibrations has been performed. For this purpose, the formulae for higher-order elements of tensor of vibrations form have been obtained, on the basis of which, in accordance with an order of disturbance theory, the changes in intramolecular dynamic parameters and coefficients of kinematic interactions of excited vibrational states form, and the change in the elements of matrix for the n-order of disturbance theory have been determined.

Citation Download Citation

Svetlana P. Gavva "Projectors theory use for research into molecular parameters of excited vibrational states", Proc. SPIE 5311, 14th Symposium on High-Resolution Molecular Spectroscopy, (12 January 2004); https://doi.org/10.1117/12.545617

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