Vibrational dependence of mean polarizability of quasi-rigid molecules

Vladimir M. Mikhailov; Valentina N. Stroinova

doi:10.1117/12.412000

29 December 2000 Vibrational dependence of mean polarizability of quasi-rigid molecules

Vladimir M. Mikhailov, Valentina N. Stroinova

Proceedings Volume 4341, Seventh International Symposium on Atmospheric and Ocean Optics; (2000) https://doi.org/10.1117/12.412000
Event: 7th International Symposium on Atmospheric and Ocean Optics, 2000, Tomsk, Russian Federation

Abstract

In the paper the conception of Pade-approximants in the framework of broadening theory of spectral lines was presented as an example of the generation of effective polarizability operators in excited vibrational states of three atomic quasi- rigid molecules. This conception is a part of the theory of linked ordering schemes of intra- and intermolecular interactions in polyatomic molecules. In the framework of the theory of linked ordering schemes in the limited ordering scheme corresponding to super excited oscillator model the vibrational dependence of mean polarizability for H₂O molecule in the form of Taylor series on the power of vibrational quantum numbers is proved. Taylor series was summed up using Pade-approximants technique.

Citation Download Citation

Vladimir M. Mikhailov and Valentina N. Stroinova "Vibrational dependence of mean polarizability of quasi-rigid molecules", Proc. SPIE 4341, Seventh International Symposium on Atmospheric and Ocean Optics, (29 December 2000); https://doi.org/10.1117/12.412000

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