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The basic spectroscopic properties of Cr3+:LaP5O14 glass have been investigated. Weak crystal field (Dq equals 2.12) and strong electron-phonon coupling lead to a broad 4A2 yield 4T2 luminescence in 720 - 1120 nm range. The measured and calculated results also show it has a rather large absorption and emission cross- sections. This kind of glass can be considered as a material for tunable infrared laser.
Jin Kai Chen,Wenqin Wang,Jinxin Zhang,Meiqin Wu, andXiaobo Chen
"Spectroscopic properties of Cr3+x:La1-xP5O14 glass", Proc. SPIE 2897, Electro-Optic and Second Harmonic Generation Materials, Devices, and Applications, (3 October 1996); https://doi.org/10.1117/12.252985
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Jin Kai Chen, Wenqin Wang, Jinxin Zhang, Meiqin Wu, Xiaobo Chen, "Spectroscopic properties of Cr3+x:La1-xP5O14 glass," Proc. SPIE 2897, Electro-Optic and Second Harmonic Generation Materials, Devices, and Applications, (3 October 1996); https://doi.org/10.1117/12.252985