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In the paper, 4-n-butoxy carboyl-methyl-urethane was synthesized by the reaction of 5,7- dodecadiyn-1, 12-diol-bis-chloro-formate with buthylaminoacetate hydrochloride. High conversion of monomer in solid state into polymer was obtained by (lambda) -irradiation. We fabricated high optical quality waveguiding film and measured the optical limiting effect of poly-4BCMU in chloride and nonlinear response time of poly-4BCMU.
Hongyao Xu,Jianghong Wang,Peiwang Zhu,Congxuan Yu,Yinglin Song,Chunfei Li,Yurui Li,Yunan Sun,Fang Cui,Songbin Zhang,Zongju Xia, andYinghua Zou
"Novel synthesis method: nonlinear optical properties of 4-n-butoxy carboyl-methyl-urethane polydiacetylene", Proc. SPIE 2321, Second International Conference on Optoelectronic Science and Engineering '94, (5 August 1994); https://doi.org/10.1117/12.182163
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