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The Czochralski crystal growth of calcium fluorapatite Ca5(PO4)3F and calcium- strontium fluorapatite (Ca1-xSrx)5(PO4)3F is reported. The growth conditions for producing the rare earth and chromium doped crystals of high quality are presented. The influence of the replacement of some calcium for strontium in FAP on crystal quality and on spectroscopic properties is discussed.
G. B. Loutts andBruce H. T. Chai
"Growth of high-quality single crystals of FAP (Ca5(PO4)3F) and its isomorphs", Proc. SPIE 1863, Growth, Characterization, and Applications of Laser Host and Nonlinear Crystals II, (21 July 1993); https://doi.org/10.1117/12.149284
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G. B. Loutts, Bruce H. T. Chai, "Growth of high-quality single crystals of FAP (Ca5(PO4)3F) and its isomorphs," Proc. SPIE 1863, Growth, Characterization, and Applications of Laser Host and Nonlinear Crystals II, (21 July 1993); https://doi.org/10.1117/12.149284