In this work, we exploit HHG in a noble gas to merge the azimuthally twisted wavefront of a vortex beam and the spatially varying polarization of a vector beam, yielding EUV vector-vortex beams (VVB) that are tailored simultaneously in their SAM and OAM. Employing a high-resolution EUV Hartmann wavefront sensor (EUV HASO, Imagine Optic), we perform the complete spatial intensity and wavefront characterization of the vertical polarization component of the 25th harmonic beam centered at a wavelength of 32.6 nm. By driving the HHG using IR VVB, we show that HHG enables the production of EUV VVB exhibiting radial, azimuthal, or even intermediate polarization distribution. Furthermore, the wavefront characterization allows for the unambiguous confirmation of the topological charge and OAM helicity of the upconverted harmonic VVB. Notably, our work reveals that HHG provides a means for the synchronous and controlled manipulation of SAM and OAM. The production of ultrafast EUV VVB with high OAM and adjustable polarization distributions opens up promising prospects for their applications at nanometric spatial and sub-femtosecond temporal resolutions using a table-top harmonic source.
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